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How's it work? Ha! The underlying principles are quite simple, really. The gun's pyreliophorite crystal— Pyreliophorite? It's an Ionian crystal which bears some resemblance to rudimentary perovskite, which is, as you should know, a crystal with unique photovoltaic properties— Photovoltaic? It means "regarding the conversion of light into electricity." No, no, the gun doesn't create electricity; the gun induces an external combustion reaction. It's perovskite that— I just explained the perovskite! If you'd stop interrupting— Wait. I remember you. You're one of Cayde's Hunters! Get out of here! Shoo! The Cryptarchy wants nothing to do with you!
Source: Exotic engrams; extremely rare world drops.